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6 μ m PET aluminum plated film · Ultra thin metallization and composite current collector scheme
In the field of metalized thin films and flexible electronics, substrate thickness is a physical quantity that is continuously compressed. The thickness of PET film has gradually decreased from 50 μ m and 25 μ m in the early days to 12 μ m and 6 μ m, and now it has been advanced to 4 μ m or even 3.1 μ m. 6 μ m is at the core of this ultra-thin range - maintaining sufficient mechanical strength to support mass production and processing, while achieving significant benefits in thinning and thinning.
What is the concept of 6 μ m? The diameter of a standard adult hair is approximately 60-80 μ m. The thickness of 6 μ m PET film is only about one tenth of the diameter of a hair.Advanced Institute of TechnologyThe thickness of PET film can be accurately controlled within the range of 4-100 μ m, with 6 μ m being in the extremely thin range of this range. The thickness range of PET aluminum plated film is between 5 μ m and 125 μ m, with 6 μ m located at the extremely thin end of this range. At this scale, PET film faces significant process challenges in coating, rewinding, and winding processes, but has mature mass production capabilities.
Core proposition:It is precisely this "thin enough and mass-produced" engineering positioning that makes 6 μ m PET aluminum plated film irreplaceable in applications such as metalized thin film capacitors and lithium battery composite current collectors.
In metallized film capacitors, PET film serves as the dielectric, and its thickness directly determines the volumetric efficiency of the capacitor. The capacitance of a capacitor is inversely proportional to the thickness of the dielectric - the thinner the film, the greater the capacitance within the same volume.
The capacitor with PET as the dielectric is called Mylar capacitor. The dielectric constant of PET film is about 3.0-3.8 at a frequency of 1MHz, with a dielectric loss of less than 0.008. The working temperature range covers -40 ° C to 125 ° C. The thickness of the metallized electrode is only 50 to 100nm, which not only reduces contact resistance but also has a certain self-healing ability. When the dielectric partially breaks down, the extremely thin metal layer rapidly evaporates around the breakdown point, allowing the capacitor to resume normal operation.
6 μ m is at a critical balance between high volumetric efficiency and process feasibility. Metallized PET film capacitors are widely used in fields such as consumer electronics, automotive electronics, and industrial power supplies. Aluminum metallized polyester film with a thickness of 2 microns to 12 microns is the standard specification for manufacturing capacitors. The mass production capability of 6 μ m PET aluminum coated film is a crucial step in the direction of ultra-thin technology, moving from being "feasible" to being "user-friendly".
The application of 6 μ m PET aluminum coated film in the field of lithium battery composite current collectors is one of the most concerned technological directions in recent years.
The composite current collector adopts a sandwich structure of "metal conductive layer polymer material support layer metal conductive layer", with a PET or other polymer base film in the middle and aluminum or copper plated metal layers on the outer two layers. PET composite aluminum foil is made of 6 μ m PET as the substrate, and then coated with 1 μ m aluminum layers on both sides, with a total thickness of 8 μ m, compared to 10 μ m rolled aluminum foil. Compared with traditional current collectors, composite current collectors have advantages such as high safety, low manufacturing cost, and strong compatibility.
Composite aluminum foil with PET as the support layer (thickness 6 μ m, surface density 8.3g/m ²) reduces weight by 36.7% compared to 8 μ m pure aluminum foil (surface density 21.6g/m ²); Composite copper foil reduces weight by up to 60% compared to pure copper foil. Lightweight plastic film, as an intermediate support layer to replace some metals, is the core source of weight reduction for composite current collectors. According to BYD's patent data, if composite current collectors are used for both positive and negative electrodes, the energy density is expected to increase by 6% compared to pure copper aluminum foil batteries.
The intermediate support layer can effectively reduce the generation of metal burrs in the battery under abnormal external forces, preventing them from penetrating the diaphragm and causing internal short circuits; Polymer ductility is generally stronger than that of metal layers, and composite current collectors have thermal runaway prevention effects such as longitudinal fracture and transverse insulation. They can significantly improve battery safety performance under extreme abuse conditions such as needle punching. In terms of manufacturing process, composite aluminum foil mainly adopts vacuum evaporation coating process.
The aluminum layer of 6 μ m PET aluminum coated film was prepared using vacuum evaporation technology. In a vacuum environment, high-purity aluminum is heated to the evaporation temperature, causing aluminum vapor to condense and deposit on the surface of high-speed PET film, forming a continuous and dense aluminum layer. Vacuum evaporation is the process of placing a roll of film in a vacuum chamber. When the vacuum degree reaches 5.0 × 10 ² Pa or higher, the evaporation boat is heated to 1300 ℃ to 1400 ℃, and then aluminum wire with a purity of 99.9% is continuously sent to the evaporation boat for evaporation. The aluminum vapor condenses and deposits on the surface of the PET film to form a coating.
Vacuum deposition on ultra-thin substrates with a thickness of 6 μ m faces a series of technical challenges that are far more stringent than conventional thickness substrates:
If the winding tension is too high, the film will be "squeezed" out, wrinkled, or even stretched and deformed; If the tension is too low, it is easy to cause detachment. The thinner the substrate thickness, the narrower the tension control window.
The temperature resistance of PET film is about 180 ° C, while the evaporation temperature of aluminum can reach 1200 to 1400 ° C. The evaporation process requires temperature control, and excessive substrate temperature can cause defects such as deformation, uneven surface thickness, or cracking.
The lack of active functional groups on the surface of PET material and insufficient adhesion between the metal coating and the substrate can lead to the detachment of the aluminum layer during subsequent processing or capacitor operation. Advanced Institute Technology adopts plasma online cleaning and activation technology to pre treat the surface of PET film, effectively improving the bonding strength between the aluminum layer and the substrate.
On a very thin substrate of 6 μ m, any tiny substrate defects or dust particles can become penetrating pinholes. Advanced Institute Technology minimizes pinhole defects by accurately controlling the matching relationship between evaporation rate and substrate operating speed.
Based on a 6 μ m PET substrate, aluminum plated film products with different aluminum layer thicknesses can be prepared by precisely controlling the evaporation process parameters. The thickness of the aluminum layer is usually characterized by optical density (OD). Optical density is the logarithm of the ratio of incident light to transmitted light, calculated as OD=log ₁₀ (1/transmittance).
Industry research data shows that the optical density value of aluminum film is about 0.5 to 2.5, corresponding to a physical thickness of about 6 to 40nm. The correspondence between OD value and aluminum layer thickness can refer to the following data: OD 1.6 corresponds to an aluminum layer thickness of about 320 Å, OD 2.0 corresponds to about 400 Å, OD 2.4 corresponds to about 480 Å, and OD 2.8 corresponds to about 560 Å.
Different aluminum layer thicknesses correspond to different performance focuses:
| Product Type | Optical Density (OD) | Key Characteristics | Typical Applications |
|---|---|---|---|
| 6 0.12PET aluminum plated film | ~0.12 OD | Extremely thin aluminum layer, semi transparent, extremely flexible | Ultra thin capacitors, precision optical films, low barrier packaging |
| 6 0.5PET aluminum plated film | ~0.5 OD | Thin aluminum layer, good flexibility, moderate barrier properties | Metallized film capacitors, electronic shielding |
| 6 0.8PET aluminum plated film | ~0.8 OD | Medium aluminum layer, high reflectivity, strong conductivity | High reliability capacitors, electromagnetic shielding |
| 6 1PET aluminum plated film | ~1.0 OD | Thick aluminum layer, high reflectivity, low surface resistance | Lithium battery composite current collector, high-end capacitor, EMI shielding |
When selecting, engineers should weigh the requirements of capacitance density, flexibility, and barrier properties comprehensively: the lower the OD value, the better the flexibility of the film and the stronger the winding adaptability; The higher the OD value, the stronger the conductivity and barrier properties. For capacitor applications, the thickness of the aluminum layer needs to be balanced with the operating voltage and self-healing characteristics; For the application of composite current collectors, it is necessary to ensure that the surface resistance of the aluminum layer meets the conductivity requirements.
ComprehensiveAdvanced Institute of TechnologyAccording to industry public information, the key performance characteristics of 6 μ m PET aluminum plated film are as follows:
| performance metrics | typical value | Reference source |
|---|---|---|
| Dielectric constant (1MHz) | ~3.0 | — |
| Dielectric loss (1kHz) | 0.002 | — |
| dielectric strength | 17 kV/mm | — |
| Surface resistivity (after aluminum plating) | 10¹³ Ω/sq | — |
| Tensile strength (biaxial stretching) | 190–260 MPa | — |
| Temperature resistance range | -40 ° C to 125 ° C | — |
| OD range of aluminum layer | 0.12-1.0 (adjustable) | — |
This is the core application area of 6 μ m PET aluminum plated film. In miniaturized capacitors that require high capacitance density, a 6 μ m ultra-thin PET substrate can achieve higher capacitance within limited packaging space. Metallized PET film capacitors are widely used in fields such as consumer electronics, automotive electronics, and industrial power supplies.
This is the fastest-growing application area for 6 μ m PET aluminum coated film. The composite aluminum foil adopts a sandwich structure of "PET based film double-sided aluminum plating", which can replace traditional aluminum foil as the positive electrode current collector of lithium batteries. The 6 μ m PET substrate significantly reduces the weight of the composite current collector, and at the same time, the polymer material layer produces a circuit breaking effect during thermal runaway, fundamentally reducing the risk of fire caused by internal short circuits in the battery.
In electronic devices with extremely limited space, 6 μ m PET aluminum plated film can serve as an ultra-thin electromagnetic shielding layer. The aluminum layer can effectively block the penetration of electromagnetic waves and light, protecting the stability and safety of internal electronic devices.
PET aluminum plated film is widely used in packaging of food, medicine, cosmetics, and other products. Its barrier performance can extend the shelf life of the product, and the metallic luster appearance enhances the shelf appeal of the product.
When engineers choose 6 μ m PET aluminum plated film, the following dimensions deserve special attention:
Selection warning:6 μ m is the engineering balance point that is "thin enough and can be mass-produced" - it achieves the optimal solution between the benefits of thinning and the feasibility of mass production. OD value is not necessarily better the higher: capacitor applications require finding the optimal balance between volumetric efficiency, voltage resistance, and self-healing characteristics; The application of composite current collectors requires a balance between conductivity and weight reduction benefits.
The essence of 6 μ m PET aluminum coated film is to find an engineering balance between the thinning and mass production feasibility of PET film. It is significantly thinner than 12 μ m, bringing tangible volume efficiency and weight reduction benefits to the composite current collector of metalized thin film capacitors and lithium batteries; At the same time, it retains sufficient process margin to ensure stable operation of roll to roll vacuum deposition within an acceptable yield range.
From the measured data of 36.7% weight reduction of composite aluminum foil made by double-sided aluminum plating on 6 μ m PET base film, to the complete product system and customization capability covering 5 μ m to 125 μ m in the field of PET film aluminum plating by Advanced Institute Technology - behind the thickness of 6 μ m is a complete process system from substrate tension control, temperature management to coating uniformity and interface bonding guarantee. For engineers, understanding the process constraints and performance opportunities behind the thickness of 6 μ m - how OD values affect capacitance density and barrier performance, and how to choose aluminum layer thickness - is more valuable than simply remembering a specification.
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